Dr Dmitrii Rakov

Grant Funded Researcher (A)

School of Chemical Engineering

College of Engineering and Information Technology

Eligible to supervise Masters and PhD as Principal Supervisor - email supervisor to discuss availability.


Dr Rakov's research focuses on computational and experimental design and characterisation of energy storage materials, specifically liquid and polymer electrolytes for batteries, coordination chemistry, and electrodics. Additionally, Dr Rakov works on the development of electrochemical methods for recovery of critical materials from spent electronics. His research involves an understanding of transport phenomena, the kinetics of electrochemical reactions at electrified interfaces and the nature of interphase evolution. Dr Rakov also works on advancing computational chemistry methods for a deeper understanding of electrochemical processes.

Dr Rakov's research interests involve electrochemistry, energy storage, transport phenomena, physical organic chemistry, computational chemistry/physics, green chemistry and process design.

Date Type Title Institution Name Country Amount
2023 Award Best presentation (A05 symposium on sodium and zinc batteries) Electrochemical Society United States -
2023 Award Young Electrochemist Award 2022 Post-doctoral Category Australia -

Language Competency
Chinese (Mandarin) Can read, speak and understand spoken
English Can read, write, speak, understand spoken and peer review
Russian Can read, write, speak, understand spoken and peer review

Date Institution name Country Title
2022 Deakin University Australia PhD
2009 - 2015 Ural Federal University Russia Master of Science (Analytical Chemistry)

Year Citation
2025 Alghamdi, N. S., Rakov, D., Peng, X., Lee, J., Huang, Y., Yang, X., . . . Luo, B. (2025). Tailoring Zn-ion Solvation Structures for Enhanced Durability and Efficiency in Zinc-Bromine Flow Batteries. Angewandte Chemie International Edition, 64(27), e202502739-1-e202502739-10.
DOI Scopus26 WoS27 Europe PMC3
2025 Ahmed, N., Rakov, D. A., Liu, Y., Feng, J., Chen, S., Wu, Y., . . . Huang, X. (2025). Ion-Dipole Interaction Driven Alumina-Coated Polyethylene Separator with Enhanced Wettability for High-Performance Rechargeable Aluminum Batteries. Nano Letters, 25(32), 12326-12333.
DOI Scopus2 WoS2
2025 Li, M., Rakov, D. A., Fan, Y., Wang, C., Wang, C., Yuwono, J. A., . . . Guo, Z. (2025). Balancing Solvation Ability of Polymer and Solvent in Gel Polymer Electrolytes for Efficient Lithium Metal Batteries. Angewandte Chemie International Edition, 64(41), e202513450-1-e202513450-11.
DOI Scopus19 WoS18 Europe PMC6
2024 Rakov, D. A., Ahmed, N., Kong, Y., Nanjundan, A. K., Popov, I., Sokolov, A. P., . . . Yu, C. (2024). Exploring the Impact of In Situ-Formed Solid-Electrolyte Interphase on the Cycling Performance of Aluminum Metal Anodes. ACS Nano, 18(41), 28456-28468.
DOI Scopus12 WoS12 Europe PMC4
2023 Rakov, D. A. (2023). Metal-doped nickel-based chalcogenides and phosphochalcogenides for electrochemical water splitting. Energy Advances, 2(2), 235-251.
DOI Scopus19 WoS19
2023 Rakov, D. A., Sun, J., Cherepanov, P. V., Arano, K., Howlett, P. C., Simonov, A. N., . . . Forsyth, M. (2023). The impact of electrode conductivity on electrolyte interfacial structuring and its implications on the Na⁰⁄⁺ electrochemical performance. Energy and Environmental Science, 16(9), 3919-3931.
DOI Scopus24 WoS24
2022 Pal, U., Rakov, D., Lu, B., Sayahpour, B., Chen, F., Roy, B., . . . Forsyth, M. (2022). Interphase control for high performance lithium metal batteries using ether aided ionic liquid electrolyte. Energy and Environmental Science, 15(5), 1907-1919.
DOI Scopus134 WoS134
2022 Rakov, D., Hasanpoor, M., Baskin, A., Lawson, J. W., Chen, F., Cherepanov, P. V., . . . Forsyth, M. (2022). Stable and Efficient Lithium Metal Anode Cycling through Understanding the Effects of Electrolyte Composition and Electrode Preconditioning. Chemistry of Materials, 34(1), 165-177.
DOI Scopus52 WoS50
2022 Sun, J., Rakov, D., Wang, J., Hora, Y., Laghaei, M., Byrne, N., . . . Forsyth, M. (2022). Sustainable Free‐Standing Electrode from Biomass Waste for Sodium‐Ion Batteries. ChemElectroChem, 9(16), 8 pages.
DOI Scopus21 WoS15
2022 Rakov, D. A., Sun, J., Ferdousi, S. A., Howlett, P. C., Simonov, A. N., Chen, F., & Forsyth, M. (2022). Polar Organic Cations at Electrified Metal with Superconcentrated Ionic Liquid Electrolyte and Implications for Sodium Metal Batteries. ACS Materials Letters, 4(10), 1984-1990.
DOI Scopus23 WoS23
2022 Kong, Y., Tang, C., Lei, C., Nanjundan, A. K., Chen, S., Ahmed, N., . . . Yu, C. (2022). Enabling two-electron redox chemistry of P-type organic cathode for high-capacity aluminium-ion batteries. Nano Energy, 102, 107727-1-107727-8.
DOI Scopus23
2021 Arano, K., Begic, S., Chen, F., Rakov, D., Mazouzi, D., Gautier, N., . . . Dupre, N. (2021). Tuning the Formation and Structure of the Silicon Electrode/Ionic Liquid Electrolyte Interphase in Superconcentrated Ionic Liquids. ACS Applied Materials and Interfaces, 13(24), 28281-28294.
DOI Scopus37 WoS33 Europe PMC6
2021 Pathirana, T., Rakov, D. A., Chen, F., Forsyth, M., Kerr, R., & Howlett, P. C. (2021). Improving Cycle Life through Fast Formation Using a Superconcentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries. ACS Applied Energy Materials, 4(7), 6399-6407.
DOI Scopus31 WoS29
2021 Rakov, D., Sun, C., Lu, Z., Li, S., & Xu, P. (2021). NiSe@Ni<sub>1−<i>x</i></sub>Fe<sub><i>x</i></sub>Se<sub>2</sub> Core–Shell Nanostructures as a Bifunctional Water Splitting Electrocatalyst in Alkaline Media. Advanced Energy and Sustainability Research, 2(11), 7 pages.
DOI Scopus18 WoS17
2020 Rakov, D. A., Chen, F., Ferdousi, S. A., Li, H., Pathirana, T., Simonov, A. N., . . . Forsyth, M. (2020). Engineering high-energy-density sodium battery anodes for improved cycling with superconcentrated ionic-liquid electrolytes. Nature Materials, 19(10), 1096-1101.
DOI Scopus248 WoS242 Europe PMC105
2019 Forsyth, M., Hilder, M., Zhang, Y., Chen, F., Carre, L., Rakov, D. A., . . . Howlett, P. C. (2019). Tuning Sodium Interfacial Chemistry with Mixed-Anion Ionic Liquid Electrolytes. ACS Applied Materials and Interfaces, 11(46), 43093-43106.
DOI Scopus58 WoS56 Europe PMC13
2019 Niu, S., Sun, Y., Sun, G., Rakov, D., Li, Y., Ma, Y., . . . Xu, P. (2019). Stepwise Electrochemical Construction of FeOOH/Ni(OH)2 on Ni Foam for Enhanced Electrocatalytic Oxygen Evolution. ACS Applied Energy Materials, 2(5), 3927-3935.
DOI Scopus121 WoS118
2018 Rakov, D., Li, Y., Niu, S., & Xu, P. (2018). Insight into Mn and Ni doping of Ni1-xMnxPS3 and Mn1-xNixPS3 nanosheets on electrocatalytic hydrogen and oxygen evolution activity. Journal of Alloys and Compounds, 769, 532-538.
DOI Scopus27 WoS26
2018 Ma, Y., Chu, J., Li, Z., Rakov, D., Han, X., Du, Y., . . . Xu, P. (2018). Homogeneous Metal Nitrate Hydroxide Nanoarrays Grown on Nickel Foam for Efficient Electrocatalytic Oxygen Evolution. Small, 14(52), 7 pages.
DOI Scopus69 WoS66 Europe PMC22
2018 Li, Y., Niu, S., Rakov, D., Wang, Y., Cabán-Acevedo, M., Zheng, S., . . . Xu, P. (2018). Metal organic framework-derived CoPS/N-doped carbon for efficient electrocatalytic hydrogen evolution. Nanoscale, 10(15), 7291-7297.
DOI Scopus117 WoS109 Europe PMC24
2017 Li, K., Rakov, D., Zhang, W., & Xu, P. (2017). Improving the intrinsic electrocatalytic hydrogen evolution activity of few-layer NiPS3 by cobalt doping. Chemical Communications, 53(58), 8199-8202.
DOI Scopus73 WoS72 Europe PMC24

Year Citation
2026 Rakov, D. A., Hamza, M. A., Ahmed, N., GarcĂ­a, Y., Luo, B., Atkin, R., . . . Yu, C. (2026). Strongly Coordinated Al3+ Complex Formation Prevents Reversible Electrochemical Cycling in Haloaluminate-Free Ionic Liquids.
DOI
2023 Rakov, D., Sun, J., Cherepanov, P., Arano, K., Howlett, P., Simonov, A., . . . Forsyth, M. (2023). Impact of the electrode conductivity on the electrolyte interfacial structuring and its implications to the Na0/+ electrochemical performance.
DOI
2021 Pathirana, T., Rakov, D., Chen, F., Forsyth, M., Kerr, R., Howlett, P., & A. Rakov, D. (2021). Improving Cycle Life Through Fast Formation Using a Super-Concentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries.
DOI
2021 Pal, U., Rakov, D., Lu, B., Sayahpour, B., Chen, F., Roy, B., . . . Forsyth, M. (2021). Interphase Control in Lithium Metal Batteries Through Electrolyte Design.
DOI
2021 Pathirana, T., Rakov, D., Chen, F., Forsyth, M., Kerr, R., & Howlett, P. C. (2021). Improving Cycle Life Through Fast Formation Using a Super-Concentrated Phosphonium Based Ionic Liquid Electrolyte for Anode-Free and Lithium Metal Batteries.
DOI
2020 Rakov, D., Chen, F., Ferdousi, S., Li, H., Pathirana, T., Simonov, A., . . . Forsyth, M. (2020). Engineering High Energy Density Sodium Battery Anodes for Improved Cycling with Superconcentrated Ionic Liquid Electrolytes.
DOI

Awarded grants:

2024, Funding source: Australian Synchrotron, Melbourne, Australia. Australian Synchrotron Beamline grant (ID: 21151).

2023, Funding source: ARC Australia's Economic Accelerator (AEA), Australia Research grant for design of commercial rechargeable aluminium battery prototype (Project ID: AE230100223)

2023, Funding source: National Computational Infrastructure, Canberra, Australia HPC simulation grant from NCI Adapter scheme Q2 (ur31 project)

2023, Travel grant for the 243rd Electrochemical Society meeting, Boston, MA, USA

2022, Funding source: National Computational Infrastructure, Canberra, Australia HPC simulation grant from NCI Adapter scheme Q4 (ur31 project)

2022, Travel grant for the 242nd Electrochemical Society meeting, Atlanta, GA, USA

MAT ENG 7101 - Materials Characterisation (Teaching assistant)

Date Role Research Topic Program Degree Type Student Load Student Name
2026 Co-Supervisor Developing an all-solid-state electrolyte based on zwitterionic polymers Doctor of Philosophy Doctorate Full Time Mr Yuze Liu
2026 Principal Supervisor Theoretical Calculation-Assisted Experimental Design for Unveiling Dendrite Inhibition Strategies and Mechanisms in Metal Anodes Doctor of Philosophy Doctorate Full Time Miss Zhenzhen Wang
2026 Principal Supervisor Structural Modulation Strategies of Non-flammable Electrolytes Doctor of Philosophy Doctorate Full Time Mr Baozhen Yang
2026 Co-Supervisor Recycling of critical minerals via subcritical leaching Doctor of Philosophy Doctorate Part Time Mr Mike Jureidini

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